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Applied Chemicals and Materials Division

Reaction:   cis-2-methyl-2-hydroperoxy-2,3-dihydro-furan-3-yloxy → cis-2-methyl-3-hydroxy-2,3-dihydro-furan-2-ylperoxy
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   1.45x10¹¹ [s^-1] (T/298 K)^0.26 e^{418 [J/mole]/RT}
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory.

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Rate constant values calculated from the Arrhenius expression: