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Author(s):   Tsang, W.; Robaugh, D.; Mallard, W.G.
Title:   Single-pulse shock-tube studies on C-NO2 bond cleavage during the decomposition of some nitro aromatic compounds
Journal:   J. Phys. Chem.
Volume:   90
Year:   1986
Reference type:   Journal article
Squib:   1986TSA/ROB5968

Reaction:   Benzene,1-methyl-2-nitro-NO2 + 2-methylphenyl
Reaction order:   1
Reference reaction:   1,2-DimethylcyclohexeneC2H4 + CH2=C(CH3)C(CH3)=CH2
Temperature:   1070 - 1180 K
Pressure:  3.55 - 4.56 bar
Rate expression:   6.4x1014 [s-1] e-256917 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1070 1.84E2
1075 2.10E2
1100 4.04E2
1125 7.54E2
1150 1.37E3
1175 2.43E3
1180 2.71E3