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Title: Single-pulse shock-tube studies on C-NO2 bond cleavage during the decomposition of some nitro aromatic compounds
Journal: J. Phys. Chem.
Volume: 90
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986TSA/ROB5968
Reaction:
Benzene, 1-methyl-4-nitro- → 4-methylphenyl + NO2
Reaction order:
1
Reference reaction:
1,2-Dimethylcyclohexene → C2H4 + CH2=C(CH3)C(CH3)=CH2
Temperature:
1070 - 1180
K
Pressure: 3.44 - 4.45 bar
Rate expression:
7.69x1014 [s-1] e-268557 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1070 | 5.97E1 |
| 1075 | 6.87E1 |
| 1100 | 1.36E2 |
| 1125 | 2.61E2 |
| 1150 | 4.87E2 |
| 1175 | 8.86E2 |
| 1180 | 9.95E2 |