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Author(s):   Bouwman, J.; Fournier, M.; Sims, I. R.; Leone, S. R.; Wilson, K. R.
Title:   Reaction Rate and Isomer-Specific Product Branching Ratios of C2H + C4H8: 1-Butene, cis-2-Butene, trans-2-Butene, and Isobutene at 79 K
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   5093 - 5105
Year:   2013
Reference type:   Journal article
Squib:   2013BOU/FOU5093-5105

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2013BOU/FOU5093-5105   1-C4H8 + ·C2H → Products  79.00   1.90E-10              2
  2013BOU/FOU5093-5105   (Z)-2-C4H8 + ·C2H → Products  79.00   1.70E-10              2
  2013BOU/FOU5093-5105   (E)-2-C4H8 + ·C2H → Products  79.00   2.10E-10              2
  2013BOU/FOU5093-5105   Isobutene + ·C2H → Products  79.00   1.80E-10              2
  2013BOU/FOU5093-5105   1-C4H8 + ·C2HVinylacetylene + ·C2H5  79.00   0.65              2
  Reference reaction:  1-C4H8 + ·C2H → Products 2
  2013BOU/FOU5093-5105   1-C4H8 + ·C2HCH2=CHCH2C≡CH + ·CH3  79.00   0.35              2
  Reference reaction:  1-C4H8 + ·C2H → Products 2
  2013BOU/FOU5093-5105   (E)-2-C4H8 + ·C2HCH3CH=CHC≡CH + ·CH3  79.00   1.00              2
  Reference reaction:  (E)-2-C4H8 + ·C2H → Products 2
  2013BOU/FOU5093-5105   (Z)-2-C4H8 + ·C2HCH3CH=CHC≡CH + ·CH3  79.00   1.00              2
  Reference reaction:  (Z)-2-C4H8 + ·C2H → Products 2
  2013BOU/FOU5093-5105   Isobutene + ·C2HCH3CH=CHC≡CH + ·CH3  79.00   0.26              2
  Reference reaction:  Isobutene + ·C2H → Products 2
  2013BOU/FOU5093-5105   Isobutene + ·C2HCH2=C(CH3)C≡CH + ·CH3  79.00   0.35              2
  Reference reaction:  Isobutene + ·C2H → Products 2
  2013BOU/FOU5093-5105   Isobutene + ·C2H → (CH3)2C=CH-C≡CH +   79.00   0.39              2
  Reference reaction:  Isobutene + ·C2H → Products 2

Search returned 11 records.