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Accessibility information
Author(s):   Al-Niami, K.; Holbrook, K.A.; Oldershaw, G.A.
Title:   Reactions of methyl radicals with cyclohexane and methyl-substituted cyclohexanes
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   85
Page(s):   1601 - 1608
Year:   1989
Reference type:   Journal article
Squib:   1989ALN/HOL1601-1608

Reaction:   Methylcyclohexane + ·CH3 → Other Products + CH4
Reaction order:   2
Temperature:   373 - 473 K
Pressure:  8.00E-2 - 0.16 bar
Rate expression:   1.94x10-12 [cm3/molecule s] e-36002 [±720 J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
373 1.77E-17
375 1.88E-17
400 3.87E-17
425 7.31E-17
450 1.29E-16
473 2.05E-16