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Author(s):   Hasson, A.S.; Tyndall, G.S.; Orlando, J.J.; Singh, S.; Hernandez, S.Q.; Campbell, S.; Ibarra, Y.
Title:   Branching Ratios for the Reaction of Selected Carbonyl-Containing Peroxy Radicals with Hydroperoxy Radicals
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   6264 - 6281
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012HAS/TYN6264-6281

Reaction:   CH3CH2CH2CHO + ·ClHCl + CH3CH2CH2CO
Reaction order:   2
Reference reaction:   CH3CH2CH2CHO + ·Cl → Products
Reference reaction order:   2
Temperature:   295 K
Pressure:  1.07 bar
Rate expression:   6.5x10-1±1.0x10-1
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   GC, HPLC< and GC/MS were used for product analysis. The experimental system was modeled using a kinetic mechanism. The uncertainties in the reported branching ratios are determined by propagating the estimated uncertainty in the model fit to the experimental data with the uncertainties in the experimental product yields.

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