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Author(s):   Cadman, P.; Tilsley, G.M.; Trotman-Dickenson, A.F.
Title:   Reactions of trichlorosilyl radicals with n-propyl chloride, cyclopentyl chloride, and carbon tetrachloride
Journal:   J. Chem. Soc. A
Page(s):   1370 - 1372
Year:   1969
Reference type:   Journal article
Squib:   1969CAD/TIL1370-1372

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1969CAD/TIL1370-1372   CCl4 + SiCl3·CCl3 + SiCl4  353 - 553   42.60       -1.41E04      2
  Reference reaction:  CH3Br + SiCl3·CH3 + Silane, bromotrichloro- 2
  1969CAD/TIL1370-1372   CCl4 + SiCl3·CCl3 + SiCl4  353 - 553   11.50       -8398      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1969CAD/TIL1370-1372   1-C4H9Cl + SiCl31-C4H9 + SiCl4  353 - 443   2.50       -5396      2
  Reference reaction:  Cyclopentane, chloro- + SiCl3Cyclopentyl + SiCl4 2
  1969CAD/TIL1370-1372   n-C3H7Cl + SiCl31-C3H7 + SiCl4  353 - 483   1.26       -4598      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1969CAD/TIL1370-1372   n-C3H7Cl + SiCl31-C3H7 + SiCl4  353 - 483   0.96       665      2
  Reference reaction:  1-C4H9Cl + SiCl31-C4H9 + SiCl4 2
  1969CAD/TIL1370-1372   Cyclopentane, chloro- + SiCl3Cyclopentyl + SiCl4  353 - 443   0.52       -1.06E04      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2

Search returned 6 records.