Author(s):   Ezell, M.J.; Wang, W.; Ezell, A.A.; Soskin, G.; Finlayson-Pitts, B.J.
Title:   Kinetics of Reactions of Chlorine Atoms with a Series of Alkenes at 1 atm and 298 K: Structure and Reactivity
Journal:   Phys. Chem. Chem. Phys.
Volume:   1
Page(s):   5813 - 5820
Year:   2002
Reference type:   Journal article
Squib:   2002EZE/WAN5813-5820

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
2002EZE/WAN5813-5820	1-C₇H₁₆ + ·Cl → Products	298	3.97E-10	3.97E-10	2
2002EZE/WAN5813-5820	CH₃CH=CH₂ + ·Cl → Products	298	2.64E-10	2.64E-10	2
2002EZE/WAN5813-5820	CH₃CH=CH₂ + ·Cl → Products	298	0.66	0.66	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	1-C₄H₈ + ·Cl → Products	298	0.85	0.85	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	Isobutene + ·Cl → Products	298	3.38E-10	3.38E-10	2
2002EZE/WAN5813-5820	Isobutene + ·Cl → Products	298	3.40E-10	3.40E-10	2
2002EZE/WAN5813-5820	Isobutene + ·Cl → Products	298	0.85	0.85	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	(E)-2-C₄H₈ + ·Cl → Products	298	0.83	0.83	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	(E)-2-C₄H₈ + ·Cl → Products	298	3.31E-10	3.31E-10	2
2002EZE/WAN5813-5820	(Z)-2-C₄H₈ + ·Cl → Products	298	3.76E-10	3.76E-10	2
2002EZE/WAN5813-5820	(Z)-2-C₄H₈ + ·Cl → Products	298	0.95	0.95	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	(CH₃)2C=CHCH₃ + ·Cl → Products	298	1.00	1.00	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	(CH₃)2CHCH=CH₂ + ·Cl → Products	298	0.83	0.83	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	C₂H₅C(CH₃)=CH₂ + ·Cl → Products	298	0.90	0.90	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	1-C₅H₁₀ + ·Cl → Products	298	1.00	1.00	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	1-C₅H₁₀ + ·Cl → Products	298	3.97E-10	3.97E-10	2
2002EZE/WAN5813-5820	(CH₃)2C=CHCH₃ + ·Cl → Products	298	3.95E-10	3.95E-10	2
2002EZE/WAN5813-5820	(CH₃)2CHCH=CH₂ + ·Cl → Products	298	3.29E-10	3.29E-10	2
2002EZE/WAN5813-5820	C₂H₅C(CH₃)=CH₂ + ·Cl → Products	298	3.58E-10	3.58E-10	2
2002EZE/WAN5813-5820	(C₂H₅)2C=CH₂ + ·Cl → Products	298	3.89E-10	3.89E-10	2
2002EZE/WAN5813-5820	(Z)-(CH₃)2CHCH=CHCH₃ + ·Cl → Products	298	4.11E-10	4.11E-10	2
2002EZE/WAN5813-5820	C₂H₅CH(CH₃)CH=CH₂ + ·Cl → Products	298	3.85E-10	3.85E-10	2
2002EZE/WAN5813-5820	C₂H₅CH(CH₃)CH=CH₂ + ·Cl → Products	298	0.97	0.97	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	(Z)-(CH₃)2CHCH=CHCH₃ + ·Cl → Products	298	1.03	1.03	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2
2002EZE/WAN5813-5820	(C₂H₅)2C=CH₂ + ·Cl → Products	298	0.98	0.98	2
Reference reaction: 1-C₇H₁₆ + ·Cl → Products				2

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