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Accessibility information
Author(s):   Fujisaki, N.; Ruf, A.; Gaumann, T.
Title:   The kinetic isotope effect for the reaction of hydrogen atoms with methylcyclohexane and perdeuteromethylcyclohexane in the gas phase
Journal:   Helv. Chim. Acta
Volume:   68
Page(s):  
Year:   1985
Reference type:   Journal article
Squib:   1985FUJ/RUF1168

Reaction:   Methylcyclohexane + → Other Products + H2
Reaction order:   2
Reference reaction:   Cyclohexane-d11, methyl-d3- + → Other Products + HD
Reference reaction order:   2
Temperature:   363 - 483 K
Pressure:  1.80 bar
Rate expression:   5.11x10-1±4.1x10-2 e8564 [±258 J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Ultrasonics
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
363 8.72E0
375 7.97E0
400 6.71E0
425 5.77E0
450 5.04E0
475 4.47E0
483 4.31E0