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Author(s):   Arthur, N.L.; Gray, P.; Herod, A.A.
Title:   Methyl and trifluoromethyl radical attack on ethers
Journal:   Can. J. Chem.
Volume:   47
Page(s):  
Year:   1969
Reference type:   Journal article
Squib:   1969ART/GRA1347

Reaction:   (iso-C3H7)2O + ·CH3CH4 + (CH3)2CHC(O)(CH3)2
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   408 - 523 K
Rate expression:   2.41x10-13 [cm3/molecule s] e-32925 [±8314472 J/mole]/RT
Uncertainty:   1.01999998
Bath gas:   Acetone
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
408 1.47E-17
425 2.16E-17
450 3.63E-17
475 5.77E-17
500 8.75E-17
523 1.24E-16