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Author(s):   Bernard, F.; Papanastasiou, D.K.; Papadimitriou, V.C.; Burkholder, J.B.
Title:   Temperature Dependent Rate Coefficients for the Gas-Phase Reaction of the OH Radical with Linear (L-2, L-3) and Cyclic (D-3, D-4) Permethylsiloxanes
Journal:   J. Phys. Chem. A
Volume:   122
Page(s):   4252 - 4264
Year:   2018
Reference type:   Journal article
Squib:   2018BER/PAP4252-4264

Reaction:   Hexamethylcyclotrisiloxane + ·OH → Products
Reaction order:   2
Temperature:   294 K
Pressure:  0.40 bar
Rate expression:   8.2x10-13 [±5.0x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The reported uncertainties are 2σ. (Z)-CF3CF=CHF and CF3CF=CH2 were used as reference compounds.

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