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Title: Temperature Dependent Rate Coefficients for the Gas-Phase Reaction of the OH Radical with Linear (L-2, L-3) and Cyclic (D-3, D-4) Permethylsiloxanes
Journal: J. Phys. Chem. A
Volume: 122
Page(s): 4252 - 4264
Year: 2018
Reference type: Journal article
Squib: 2018BER/PAP4252-4264
Reaction:
Hexamethylcyclotrisiloxane + ·OH → Products
Reaction order:
2
Temperature:
294
K
Pressure: 0.40 bar
Rate expression:
8.2x10-13 [±5.0x10-14 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
The reported uncertainties are 2σ. (Z)-CF3CF=CHF and CF3CF=CH2 were used as reference compounds.
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