Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Gas-Phase Ozonolysis of Selected Olefins: The Yield of Stabilized Criegee Intermediate and the Reactivity toward SO2
Journal: J. Phys. Chem. Lett.
Volume: 3
Page(s): 2892 - 2896
Year: 2012
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2012BER/JOK2892-2896
Reaction:
(CH3)2C=C(CH3)2 + O3 → Acetone + (CH3)2C(·)OO·
Reaction order:
2
Reference reaction:
(CH3)2C=C(CH3)2 + O3 → Products
Reference reaction order:
2
Temperature:
293
K
Pressure: 1.01 bar
Rate expression:
6.2x10-1±2.8x10-1
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
Resulting error limits (root-mean-square error) include two standard deviations of statistical errors (2.2−7.5%) and an uncertainty of ±45% arising from the sulfuric acid calibration.
View full bibliographic record.