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Author(s):   Cvetanovic, R.J.; Irwin, R.S.
Title:   Rates of addition of methyl radicals to olefins in the gas phase
Journal:   J. Chem. Phys.
Volume:   46
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967CVE/IRW1694

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1967CVE/IRW1694   C2H4 + ·CH31-C3H7  353 - 453   12.60       1463      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   1-C4H8 + ·CH3 → Other Products + CH4  353 - 453   1.30       -1297      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   1-C4H8 + ·CH3 → Adduct  353 - 453   3.00       -1837      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   1,3-Butadiene + ·CH3 → Adduct  403 - 453   2.40       -1.45E04      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   CH3CH=CH2 + ·CH3 → Other Products + CH4  353 - 453   0.30       -1796      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   CH3CH=CH2 + ·CH3 → Adduct  353 - 453   4.80       -715      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   Isobutene + ·CH3 → Adduct  353 - 453   4.20       -2760      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   Isobutene + ·CH3CH4 + ·CH2C(CH3)=CH2  353 - 453   1.60       1380      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (CH3)2C=CHCH3 + ·CH3 → Other Products + CH4  403 - 453   0.90       -3933      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (CH3)2C=CHCH3 + ·CH3 → (CH3)2CHC(·)(CH3)2  403 - 453   0.40       -6485      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (CH3)2C=C(CH3)2 + ·CH3CH4 + CH2C(CH3)=C(CH3)2  403 - 453   16.60       5313      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (CH3)2C=C(CH3)2 + ·CH3 → (CH3)3C-C(·)(CH3)2  403 - 453   0.30       -3517      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (Z)-2-C4H8 + ·CH3 → Other Products + CH4  353 - 453   1.90       -166      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (Z)-2-C4H8 + ·CH3 → (CH3)2CHCH(·)CH3  353 - 453   1.30       -499      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (E)-2-C4H8 + ·CH3 → Other Products + CH4  353 - 453   3.40       2677      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2
  1967CVE/IRW1694   (E)-2-C4H8 + ·CH3 → (CH3)2CHCH(·)CH3  353 - 453   4.20       2054      2
  Reference reaction:  iso-C4H10 + ·CH3 → Other Products + CH4 2

Search returned 16 records.