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Title: Rate Constants of Nine C6-C9 Alkanes with OH from 230 to 379 K: Chemical Tracers for [OH]
Journal: J. Phys. Chem. A
Volume: 113
Page(s): 5030 - 5038
Year: 2009
Reference type: Journal article
Squib: 2009SPR/DEM5030-5038
Reaction:
Methylcyclopentane + ·OH → Products
Reaction order:
2
Temperature:
230 - 370
K
Pressure: 1.07E-2 - 1.33E-2 bar
Rate expression:
no rate data available
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Laser induced fluorescence
Comments:
Rate constants obtained at individual temperatures are reported but no Arrhenius fit is given. Instead, the temperature dependence of the rate constant is represented with a formula that is more complicated than the Arrhenius or the Modified Arrhenius equations.
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