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Title: Gas-phase pyrolyses of 1,1-dichlorobutane and 1,1-dichloropropane
Journal: J. Chem. Soc. B
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971HOL/PAR1762
Reaction:
Butane, 1,1-dichloro- → 1-Butene, 1-chloro- + HCl
Reaction order:
1
Temperature:
689 - 733
K
Pressure: 6.67E-3 - 0.20 bar
Rate expression:
4.79x1013 [s-1] e-225322 [±8314472 J/mole]/RT
Uncertainty:
1.8600000143051147
Bath gas:
Butane, 1,1-dichloro-
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 689 | 3.97E-4 |
| 700 | 7.36E-4 |
| 725 | 2.80E-3 |
| 733 | 4.21E-3 |