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Title: Measurement of rate constants and equilibrium constants of RI = R + I and I + RI = I2 + R for R = C3F7, iso-C3F7, C6F13, CF3OCF2CF2 or C3F7OCF2CF2
Journal: J. Gen. Chem. USSR
Volume: 61
Page(s): 158 - 165
Original page: 178
Year: 1991
Reference type: Journal article
Squib: 1991SKO/DYM158-165
Reaction:
CF3(CF2)4CF2I + I → CF3(CF2)4CF2 + I2
Reaction order:
2
Temperature:
560 - 700
K
Rate expression:
3.99x10-13 [cm3/molecule s] e-51965 [±1563 J/mole]/RT
Uncertainty:
2.50999999
Bath gas:
CF3(CF2)4CF2I
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 560 | 5.67E-18 |
| 575 | 7.58E-18 |
| 600 | 1.19E-17 |
| 625 | 1.81E-17 |
| 650 | 2.66E-17 |
| 675 | 3.80E-17 |
| 700 | 5.28E-17 |