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Author(s):   Wallington, T.J.; Ellermann, T.; Nielsen, O.J.; Sehested, J.
Title:   Atmospheric chemistry of FCOx radicals: UV spectra and self-reaction kinetics of FCO and FC(O)O2 and kinetics of some reactions of FCOx with O2, O3, and NO at 296 K
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   2346 - 2356
Year:   1994
Reference type:   Journal article
Squib:   1994WAL/ELL2346-2356

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1994WAL/ELL2346-2356   FCO + FCOCOF2 + CO  296   1.60E-11              2
  1994WAL/ELL2346-2356   FCO + O2FC(O)OO  296   1.20E-12              2
  1994WAL/ELL2346-2356   FCO + NO → Products  296   1.03E-12              2
  1994WAL/ELL2346-2356   O3 + FC(O)O· → Products  296   <5.99E-14              2
  1994WAL/ELL2346-2356   NO + ·FFNO  296   5.50E-12              2
  1994WAL/ELL2346-2356   NO + FC(O)O·CO2 + FNO  296   1.30E-10              2
  1994WAL/ELL2346-2356   NO + FC(O)OONO2 + FC(O)O·  296   2.51E-11              2
  1994WAL/ELL2346-2356   FC(O)O· + FC(O)O· → FC(O)OO(O)CF  296   >7.01E-13              2
  1994WAL/ELL2346-2356   FC(O)O· + FC(O)OO → Adduct  296   8.00E-12              2
  1994WAL/ELL2346-2356   FC(O)OO + FC(O)OO → FC(O)OO(O)CF + O2  298   1.20E-12           1.20E-12  3
  1994WAL/ELL2346-2356   FC(O)OO + FC(O)OOO2 + FC(O)O· + FC(O)O·  296   4.80E-12              2

Search returned 11 records.