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Title: The photolysis and thermal decomposition of pyruvic acid in the gas phase
Journal: Can. J. Chem.
Volume: 63
Page(s):
Year: 1985
Reference type: Journal article
Squib: 1985YAM/BAC549
Reaction:
CH3COCOOH → CH3CHO + CO2
Reaction order:
1
Temperature:
455 - 584
K
Pressure: 1.07E-3 - 9.33E-3 bar
Rate expression:
1.55x107 [s-1] e-115571 [J/mole]/RT
Bath gas:
CH3COCOOH
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 455 | 8.37E-7 |
| 475 | 3.03E-6 |
| 500 | 1.31E-5 |
| 525 | 4.92E-5 |
| 550 | 1.64E-4 |
| 575 | 4.92E-4 |
| 584 | 7.14E-4 |