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Author(s):   Iyer, R.S.; Rogers, P.J.; Rowland, F.S.
Title:   Thermal rate constant for addition of chlorine atoms to ethylene
Journal:   J. Phys. Chem.
Volume:   87
Page(s):   3799 - 3801
Year:   1983
Reference type:   Journal article
Squib:   1983IYE/ROG3799-3801

Reaction:   C2H4 + ·Cl → CH2CH2Cl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Temperature:   298 K
Pressure:  5.33 bar
Rate expression:   1.93x10-10 [±1.99x10-11 cm3/molecule s]
Bath gas:   CF3Cl
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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