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Author(s):   Knyazev, V.D.; Kalinovski, I.J.; Slagle, I.R.
Title:   Kinetics of the CH2CH2Cl = C2H4 + Cl reaction
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   3216 - 3221
Year:   1999
Reference type:   Journal article
Squib:   1999KNY/KAL3216-3221

Reaction:   C2H4 + ·Cl → CH2CH2Cl
Reaction order:   2
Temperature:   200 - 800 K
Rate expression:   5.15x10-11 [cm3/molecule s] (T/298 K)1.31 e4307 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
200 4.07E-10
250 3.25E-10
300 2.92E-10
350 2.79E-10
400 2.76E-10
450 2.79E-10
500 2.86E-10
550 2.95E-10
600 3.05E-10
650 3.17E-10
700 3.30E-10
750 3.44E-10
800 3.59E-10