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Accessibility information
Author(s):   Hunt, M.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   933. Pyrolyses of ethyl cyanide, t-butyl cyanide, cumyl cyanide, and acetamide, and bond strengths in cyanides
Journal:   J. Chem. Soc.
Page(s):   5074 - 5080
Year:   1965
Reference type:   Journal article
Squib:   1965HUN/KER5074-5080

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1965HUN/KER5074-5080   CH3CONH2H2C=C=O + NH3  936 - 1020   5.01E14       3.07E05      1
  1965HUN/KER5074-5080   C2H5CNC2H4 + HCN  959 - 1040   1.00E15       3.23E05      1
  1965HUN/KER5074-5080   C2H5CNCH2CHCN + H2  959 - 1040   2.51E12       2.70E05      1
  1965HUN/KER5074-5080   C2H5CN·CH3 + CH2CN  959 - 1040   1.26E14       3.04E05      1
  1965HUN/KER5074-5080   (CH3)3C-CN·CH3 + (CH3)2CCN  875 - 925   1.45E15       2.94E05      1
  1965HUN/KER5074-5080   C6H5-C(CH3)2C≡N → ·CH3 + C6H5-C(·)(CH3)C≡N  793 - 897   2.00E13       2.26E04      1

Search returned 6 records.