Author(s):   Kunz, A.; Roth, P.
Title:   High-Temperature Kinetics of Some Si- and Cl-Containing Ceramic Precursors
Journal:   Int J. Chem. Kinet.
Volume:   33
Page(s):   741 - 754
Year:   2001
Reference type:   Journal article
Squib:   2001KUN/ROT741-754

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	n	Ea [J/mole]	Order
2001KUN/ROT741-754	SiCl₄ → SiCl₃ + ·Cl	1500 - 2400	1.15E-07		3.14E05	2
2001KUN/ROT741-754	SiCl → Si + ·Cl	2300 - 3700	0.11	-7.00	4.10E05	2
2001KUN/ROT741-754	SiCl₃ → SiCl₂ + ·Cl	1500 - 3700	7.64E-09		2.73E05	2
2001KUN/ROT741-754	SiCl₂ → SiCl + ·Cl	1500 - 3700	2.82E-09		3.07E05	2
2001KUN/ROT741-754	SiCl₄ → SiCl₃ + ·Cl	1700 - 3300	8.97E-09		3.27E05	2
2001KUN/ROT741-754	SiCl₄ + ·Cl → Cl₂ + SiCl₃	1000 - 2040	<1.66E-14			2
2001KUN/ROT741-754	Si + HCl → H· + SiCl	1500 - 2900	1.58E-09		5.70E04	2
2001KUN/ROT741-754	CH₄ + Si → H₂ + SiCH₂	1500 - 2600	<1.66E-12			2
2001KUN/ROT741-754	·CH₃ + Si → SiCH + H₂	1500 - 2600	3.64E-10			2
2001KUN/ROT741-754	Si + ·CH₂ → SiC + H₂	1500 - 2600	3.32E-10			2

Search returned 10 records.