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Author(s):   Smith, G.G.; Lum, K.K.; Kirby, J.A.; Posposil, J.
Title:   Linear free-energy relationship involving ortho substituents in gas-phase reactions. XVII
Journal:   J. Org. Chem.
Volume:   34
Page(s):   2090 - 2095
Year:   1969
Reference type:   Journal article
Squib:   1969SMI/LUM2090-2095

Reaction:   Carbonic acid o-chloro-α-methylbenzyl methyl ester → 2-Chlorostyrene + CH3OC(O)OH
Reaction order:   1
Reference reaction:   Carbonic acid methyl α-methylbenzyl ester → Styrene + CH3OC(O)OH
Reference reaction order:   1
Temperature:   619 K
Rate expression:   4.8x10-1
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

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