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Accessibility information
Author(s):   Shilov, A.E.; Sabirova, R.D.
Title:   The mechanism of the thermal decomposition of ethyl and vinyl iodides and the simultaneous occurrence of two types of primary decomposition of alkyl halides
Journal:   Kinet. Catal.
Volume:   5
Page(s):   32 - 39
Year:   1964
Reference type:   Journal article
Squib:   1964SHI/SAB32-39

Reaction:   CH2=CHBrC2H2 + HBr
Reaction order:   1
Temperature:   813 - 931 K
Rate expression:   1.7x1015 [s-1] e-274378 [J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
813 4.00E-3
825 7.22E-3
850 2.34E-2
875 7.10E-2
900 2.02E-1
925 5.45E-1
931 6.86E-1