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Accessibility information
Author(s):   Cadman, P.; Engelbrecht, W.J.
Title:   A shock-wave study of the dehydrohalogenation reactions of vinyl compounds
Journal:   J. Chem. Soc. Chem. Commun.
Year:   1970
Reference type:   Journal article
Squib:   1970CAD/ENG453

Reaction:   CH2=CHBrC2H2 + HBr
Reaction order:   1
Reference reaction:   CH3CF3CH2=CF2 + HF
Temperature:   1630 - 2100 K
Rate expression:   9.55x1012 [s-1] e-261906 [J/mole]/RT
Bath gas:   CH2=CHBr
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1630 3.87E4
1650 4.89E4
1675 6.50E4
1700 8.57E4
1725 1.12E5
1750 1.45E5
1775 1.87E5
1800 2.40E5
1825 3.05E5
1850 3.85E5
1875 4.83E5
1900 6.02E5
1925 7.47E5
1950 9.21E5
1975 1.13E6
2000 1.38E6
2025 1.68E6
2050 2.03E6
2075 2.44E6
2100 2.92E6