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Author(s):   Quijano, C.; Notario, R.; Quijano, J.; Sanchez, C.; Leon, L.A.; Velez, E.
Title:   Theoretical study of the gas-phase thermolysis reaction of alkyl (ethyl, isopropyl, and tert-butyl) N,N-dimethylcarbamates and N,N-diethylcarbamates
Journal:   Theor. Chem. Acct.
Volume:   110
Page(s):   377 - 386
Year:   2003
Reference type:   Journal article
Squib:   2003QUI/NOT377-386

Reaction:   (CH3CH2)2NCO(O)CH(CH3)2 → CH3CH=CH2 + CO2 + sec-C4H9NH2
Reaction order:   1
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Comments:   Potential energy diagram was computed at the MP2/6-311++G(2d,p)//MP2/6-31G(d) level. Two transition states reside on the reaction path.

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