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Accessibility information
Author(s):   Cohen, N.; Benson, S.W.
Title:   Transition-state-theory calculations for reactions of OH with haloalkanes
Journal:   J. Phys. Chem.
Volume:   91
Page(s):   162 - 170
Year:   1987
Reference type:   Journal article
Squib:   1987COH/BEN162-170

Reaction:   CH2BrCH2Br + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   298 - 2000 K
Rate expression:   4.75x10-13 [cm3/molecule s] (T/298 K)1.70 e-1497 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.60E-13
300 2.64E-13
400 4.99E-13
500 7.99E-13
600 1.16E-12
700 1.57E-12
800 2.03E-12
900 2.55E-12
1000 3.11E-12
1100 3.71E-12
1200 4.36E-12
1300 5.06E-12
1400 5.79E-12
1500 6.57E-12
1600 7.39E-12
1700 8.25E-12
1800 9.14E-12
1900 1.01E-11
2000 1.10E-11