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Home ©NIST, 2013 Accessibility information |
Title: Gas phase pyrolysis of alkyl acetates
Journal: Recueil
Volume: 82
Page(s): 1123 - 1154
Year: 1963
Reference type: Journal article
Squib: 1963SCH/KOO1123-1154
Reaction:
2,4-Dimethyl-3-pentanol acetate → Other Products + CH3C(O)OH
Reaction order:
1
Temperature:
650 - 710
K
Rate expression:
1.1x1012 [s-1] (T/298 K)1.00 e-181255 [±1813 J/mole]/RT
Bath gas:
2,4-Dimethyl-3-pentanol acetate
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 650 | 6.52E-3 |
| 675 | 2.35E-2 |
| 700 | 7.71E-2 |
| 710 | 1.21E-1 |