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Author(s):   Wang, D.; Qian, X.; Zhang, Q.
Title:   The isonitrile-nitrile isomerization: kinetic parameters, reaction mechanism and relative photoionization cross-section of the HOMO. A HeI photoelectron spectroscopy study
Journal:   Chem. Phys. Lett.
Volume:   266
Page(s):   560 - 567
Year:   1997
Reference type:   Journal article
Squib:   1997WAN/QIA560-567

Reaction:   (CH3)3CNC(CH3)3C-CN
Reaction order:   1
Temperature:   484 - 493 K
Pressure:  1.01 bar
Rate expression:   2.97x1013 [s-1] e-164627 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (Vis-UV)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
484 5.08E-5
493 1.07E-4