Author(s):   Caralp, F.; Lesclaux, R.; Rayez, M.-T.; Rayez, J.-C.; Forst, W.
Title:   Kinetics of the combination reactions of chlorofluoromethylperoxy radicals with NO₂ in the temperature range 233-373 K
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   84
Page(s):
Year:   1988
Reference type:   Journal article
Squib:   1988CAR/LES569

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	n	k(298.00 K)	Order
1988CAR/LES569	NO₂ + CF₃O₂ → CF₃OONO₂	233 - 373	8.90E-12	-0.72	8.90E-12	2
1988CAR/LES569	NO₂ + CF₃O₂ → CF₃OONO₂	233 - 373	2.70E-29	-4.70	2.70E-29	3
1988CAR/LES569	NO₂ + CCl₃O₂ → CCl₃OONO₂	233 - 373	1.49E-11	-0.30	1.49E-11	2
1988CAR/LES569	NO₂ + CCl₃O₂ → CCl₃OONO₂	233 - 373	9.18E-29	-6.00	9.18E-29	3
1988CAR/LES569	NO₂ + CCl₂FO₂ → CFCl₂OONO₂	233 - 373	8.30E-12	-0.66	8.30E-12	2
1988CAR/LES569	NO₂ + CCl₂FO₂ → CFCl₂OONO₂	233 - 373	5.51E-29	-5.50	5.51E-29	3
1988CAR/LES569	NO₂ + CClF₂OO → CClF₂OONO₂	233 - 373	1.02E-11	-0.66	1.02E-11	2
1988CAR/LES569	NO₂ + CClF₂OO → CClF₂OONO₂	233 - 373	4.00E-29	-5.10	4.00E-29	3

Search returned 8 records.