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Author(s):   Inoue, Y.; Kawasaki, M.; Wallington, T.J.; Hurley, M.D.
Title:   Atmospheric chemistry of CF3CH2CF2CH3 (HFC-365mfc): Kinetics and mechanism of chlorine atom initiated oxidation, infrared spectrum, and global warming potential
Journal:   Chem. Phys. Lett.
Volume:   462
Page(s):   164 - 168
Year:   2008
Reference type:   Journal article
Squib:   2008INO/KAW164-168

Reaction:   CF3CH2CF2CH3 + ·Cl → Products
Reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   1.02x10-15 [±1.4x10-16 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The rate constant was calculated relative to reactions CFCl2CH3+Cl and CD4+Cl

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