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Author(s):   Singleton, D.L.; Irwin, R.S.; Cvetanovic, R.J.
Title:   Arrhenius Parameters for the Reactions of O(3P) Atoms with Several Aldehydes and the Trend in Aldehydic C-H Bond Dissociation Energies
Journal:   Can. J. Chem.
Volume:   55
Year:   1977
Reference type:   Journal article
Squib:   1977SIN/IRW3321

Reaction:   CH3CH2CH2CHO + → Other Products + ·OH
Reaction order:   2
Temperature:   298 - 472 K
Pressure:  4.00E-2 - 8.00E-2 bar
Rate expression:   1.66x10-11 [±9.96x10-13 cm3/molecule s] e-7117 [±142 J/mole]/RT
Bath gas:   CH3CH2CH2CHO
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Sensitized photolysis
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 9.39E-13
300 9.57E-13
325 1.19E-12
350 1.44E-12
375 1.69E-12
400 1.95E-12
425 2.22E-12
450 2.48E-12
472 2.71E-12