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Title: Relative Cis-Trans Isomerization Rates. Another Test of the Energy Randomization Hypothesis
Journal: J. Phys. Chem.
Volume: 78
Page(s):
Year: 1974
Reference type: Journal article
Squib: 1974BAU/YAD770
Reaction:
(Z)-2-C6H12 → (E)-2-C6H12
Reaction order:
1
Reference reaction:
(Z)-2-C4H8 → (E)-2-C4H8
Temperature:
1000 - 1150
K
Pressure: 0.24 - 0.40 bar
Rate expression:
3.98x1014 [s-1] e-276872 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1000 | 1.37E0 |
| 1025 | 3.09E0 |
| 1050 | 6.71E0 |
| 1075 | 1.40E1 |
| 1100 | 2.84E1 |
| 1125 | 5.56E1 |
| 1150 | 1.06E2 |