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 Author(s):   Heimann, G.; Warneck, P.
Title:   OH radical induced oxidation of 2,3-dimethylbutane in air
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   8403 - 8409
Year:   1992
Reference type:   Journal article
Squib:   1992HEI/WAR8403-8409

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992HEI/WAR8403-8409   (CH3)2CHO2 + (CH3)2CHO2 → iso-C3H7OH + Acetone + O2  297   5.99E-16              2
  1992HEI/WAR8403-8409   (CH3)2CHO2 + (CH3)2CHO2 → iso-C3H7OH + Acetone + O2  297   0.61              2
  Reference reaction:  (CH3)2CHO2 + (CH3)2CHO2 → Products 2
  1992HEI/WAR8403-8409   (CH3)2CHO2 + (CH3)2CHO2 → (CH3)2CHO· + (CH3)2CHO· + O2  297   4.00E-16              2
  1992HEI/WAR8403-8409   (CH3)2CHO2 + (CH3)2CHC(OO)(CH3)2 → Acetone + (CH3)2CHC(OH)(CH3)2 + O2  297   2.09E-17              2
  1992HEI/WAR8403-8409   (CH3)2CHO2 + (CH3)2CHC(OO)(CH3)2 → (CH3)2CHO· + O2 + (CH3)2CHC(O)(CH3)2  297   1.40E-17              2
  1992HEI/WAR8403-8409   (CH3)2CHC(OO)(CH3)2 + (CH3)2CHCH(CH3)CH2OO· → (CH3)2CHCH(CH3)CH2O· + O2 + (CH3)2CHC(O)(CH3)2  297   8.00E-17              2
  1992HEI/WAR8403-8409   (CH3)2CHC(OO)(CH3)2 + (CH3)2CHCH(CH3)CH2OO· → Butanal, 2,3-dimethyl- + O2 + 1-Butanol, 2,3-dimethyl-  297   1.20E-16              2
  1992HEI/WAR8403-8409   (CH3)2CHCH(CH3)CH2OO· + (CH3)2CHCH(CH3)CH2OO· → (CH3)2CHCH(CH3)CH2O· + (CH3)2CHCH(CH3)CH2O· + O2  297   4.00E-14              2
  1992HEI/WAR8403-8409   (CH3)2CHCH(CH3)CH2OO· + (CH3)2CHCH(CH3)CH2OO· → Butanal, 2,3-dimethyl- + O2 + 1-Butanol, 2,3-dimethyl-  297   5.99E-14              2
  1992HEI/WAR8403-8409   (CH3)2CHCH(CH3)CH2OO· + (CH3)2CHCH(CH3)CH2OO· → Butanal, 2,3-dimethyl- + O2 + 1-Butanol, 2,3-dimethyl-  297   0.56              2
  Reference reaction:  (CH3)2CHCH(CH3)CH2OO· + (CH3)2CHCH(CH3)CH2OO· → Products 2
Search returned 10 records.