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Title: Reactions of trichlorosilyl radicals with n-propyl chloride, cyclopentyl chloride, and carbon tetrachloride
Journal: J. Chem. Soc. A
Page(s): 1370 - 1372
Year: 1969
Reference type: Journal article
Squib: 1969CAD/TIL1370-1372
Reaction:
n-C3H7Cl + SiCl3 → 1-C3H7 + SiCl4
Reaction order:
2
Reference reaction:
CH3Cl + SiCl3 → ·CH3 + SiCl4
Reference reaction order:
2
Temperature:
353 - 483
K
Rate expression:
1.26 e4598 [J/mole]/RT
Bath gas:
SiHCl3
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 353 | 6.04E0 |
| 375 | 5.51E0 |
| 400 | 5.02E0 |
| 425 | 4.63E0 |
| 450 | 4.31E0 |
| 475 | 4.04E0 |
| 483 | 3.96E0 |