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Author(s):   LeFevre, H.F.; Kale, J.D.; Timmons, R.B.
Title:   Confirmation of the inertness of sulfur hexafluoride toward attack by CF3 and CH3 radicals
Journal:   J. Phys. Chem.
Volume:   73
Year:   1969
Reference type:   Journal article
Squib:   1969LEF/KAL1614

Reaction:   ·CF3 + SF6CF4 + SF5
Reaction order:   2
Temperature:   303 - 638 K
Rate expression:   1.66x10-13 [cm3/molecule s] e-83976 [J/mole]/RT
Activation energy is a lower limit.
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
303 5.54E-28
325 5.29E-27
350 4.87E-26
375 3.34E-25
400 1.80E-24
425 7.93E-24
450 2.97E-23
475 9.68E-23
500 2.80E-22
525 7.33E-22
550 1.76E-21
575 3.91E-21
600 8.12E-21
625 1.59E-20
638 2.21E-20