Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Kaiser, E.W.; Wallington, T.J.; Hurley, M.D.
Title:   Products and Mechanism of the Reaction of Chlorine Atoms with 3-Pentanone in 700-950 Torr of N2/O2 Diluent at 297-515 K
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   343 - 354
Year:   2010
Reference type:   Journal article
Squib:   2010KAI/WAL343-354

Reaction:   (C2H5)2CO + ·Cl → CH3CH2C(O)CH(·)CH3
Reaction order:   2
Temperature:   297 K
Pressure:  1.07 - 1.27 bar
Rate expression:   6.5x10-11 [±8.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The error limits represent the relative precision based on the uncertainty in the product yields and do not include uncertainty in the value of the rate constant of the overall reaction (taken from the literature).

View full bibliographic record.