Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Bierbach, A.; Barnes, I.; Becker, K.H.
Title:   Rate coefficients for the gas-phase reactions of bromine radicals with a series of alkenes, dienes, and aromatic hydrocarbons at 298 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   565 - 577
Year:   1996
Reference type:   Journal article
Squib:   1996BIE/BAR565-577

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1996BIE/BAR565-577   Benzene + Br· → Products  298   <1.00E-14           1.00E-14  2
  1996BIE/BAR565-577   CH2=CHCl + Br· → Products  300   7.37E-13              2
  1996BIE/BAR565-577   CH2=CHCl + Br· → Products  300   4.61              2
  Reference reaction:  C2H4 + Br· → Products 2
  1996BIE/BAR565-577   CH2=CCl2 + Br· → Products  300   3.65E-13              2
  1996BIE/BAR565-577   CH2=CCl2 + Br· → Products  300   2.29              2
  Reference reaction:  C2H4 + Br· → Products 2
  1996BIE/BAR565-577   CH2=C(CH3)CH=CH2 + Br· → Products  298   7.42E-11           7.42E-11  2
  1996BIE/BAR565-577   CH2=C(CH3)CH=CH2 + Br· → Products  298   1.29           1.29  2
  Reference reaction:  1,3-Butadiene + Br· → Products 2
  1996BIE/BAR565-577   C2HCl3 + Br· → Products  300   9.05E-14              2
  1996BIE/BAR565-577   C2HCl3 + Br· → Products  300   0.57              2
  Reference reaction:  C2H4 + Br· → Products 2
  1996BIE/BAR565-577   alpha-pinene + Br· → Products  296   2.23E-11              2
  1996BIE/BAR565-577   alpha-pinene + Br· → Products  296   2.40              2
  Reference reaction:  (E)-2-C4H8 + Br· → Products 2
  1996BIE/BAR565-577   1,4-Dimethylbenzene + Br· → Products  298   <1.00E-14           1.00E-14  2
  1996BIE/BAR565-577   1,3-Butadiene + Br· → Products  300   5.75E-11              2
  1996BIE/BAR565-577   1,3-Butadiene + Br· → Products  300   2.04              2
  Reference reaction:  (CH3)2C=C(CH3)2 + Br· → Products 2
  1996BIE/BAR565-577   Toluene + Br· → Products  298   <1.00E-14           1.00E-14  2
  1996BIE/BAR565-577   Furan + Br· → Products  298   <1.00E-14           1.00E-14  2
  1996BIE/BAR565-577   C2Cl4 + Br· → Products  298   <1.00E-14           1.00E-14  2
  1996BIE/BAR565-577   beta-pinene + Br· → Products  296   2.86E-11              2
  1996BIE/BAR565-577   beta-pinene + Br· → Products  296   3.04              2
  Reference reaction:  (E)-2-C4H8 + Br· → Products 2
  1996BIE/BAR565-577   (CH3)2C=CHCH3 + Br· → Products  300   1.91E-11              2
  1996BIE/BAR565-577   (CH3)2C=CHCH3 + Br· → Products  300   2.06              2
  Reference reaction:  (E)-2-C4H8 + Br· → Products 2
  1996BIE/BAR565-577   CH2=C(CH3)C(CH3)=CH2 + Br· → Products  298   8.17E-11           8.17E-11  2
  1996BIE/BAR565-577   CH2=C(CH3)C(CH3)=CH2 + Br· → Products  298   1.42           1.42  2
  Reference reaction:  1,3-Butadiene + Br· → Products 2
  1996BIE/BAR565-577   C2H5C(CH3)=CH2 + Br· → Products  298   1.52E-11           1.52E-11  2
  1996BIE/BAR565-577   C2H5C(CH3)=CH2 + Br· → Products  298   1.64           1.64  2
  Reference reaction:  (E)-2-C4H8 + Br· → Products 2
  1996BIE/BAR565-577   (CH3)2C=C(CH3)2 + Br· → Products  300   8.17E-11              2
  1996BIE/BAR565-577   (CH3)2C=C(CH3)2 + Br· → Products  300   3.04              2
  Reference reaction:  (E)-2-C4H8 + Br· → Products 2
  1996BIE/BAR565-577   (E)-2-C4H8 + Br· → Products  300   9.25E-12              2
  1996BIE/BAR565-577   (E)-2-C4H8 + Br· → Products  300   3.43              2
  Reference reaction:  CH3CH=CH2 + Br· → Products 2

Search returned 29 records.