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Title: Probing the Cyclic Transition State in the Reaction O(3P) + Alkyl Iodides to Form HOI: Electronic, Steric and Thermodynamic Factors Influencing the Reaction Pathway
Journal: Phys. Chem. Chem. Phys.
Volume: 2
Page(s): 853 - 860
Year: 2000
Reference type: Journal article
Squib: 2000REI/QIA853-860
Reaction:
c-C6H11I + O· → Cyclohexene + HIO
Reaction order:
2
Rate expression:
no rate data available
Category: Theory
Data type:
Mechanistic information only
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
Both discharge-flow and laser photolysis techniques used to probe the formation of gound and vibrationally excited HOI.
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