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Author(s):   Baker, R.R.; Baldwin, R.R.; Walker, R.W.
Title:   The Use of the H2 + O2 Reaction in Determining the Velocity Constants of Elementary Reactions in Hydrocarbon Oxidation
Journal:   Symp. Int. Combust. Proc.
Volume:   13
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971BAK/BAL291

Reaction:   iso-C4H10 + ·OHtert-C4H9 + H2O
Reaction order:   2
Temperature:   298 - 753 K
Rate expression:   8.8x10-11 [cm3/molecule s] e-9977 [J/mole]/RT
Uncertainty:   1.38
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.57E-12
300 1.61E-12
325 2.19E-12
350 2.85E-12
375 3.59E-12
400 4.38E-12
425 5.23E-12
450 6.12E-12
475 7.04E-12
500 7.98E-12
525 8.95E-12
550 9.93E-12
575 1.09E-11
600 1.19E-11
625 1.29E-11
650 1.39E-11
675 1.49E-11
700 1.58E-11
725 1.68E-11
750 1.78E-11
753 1.79E-11