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Author(s):   Atkinson, R.
Title:   Estimations of OH radical rate constants from H-atom abstraction from C-H and O-H bonds over the temperature range 250-1000K
Journal:   Int. J. Chem. Kinet.
Volume:   18
Year:   1986
Reference type:   Journal article
Squib:   1986ATK555

Reaction:   iso-C4H10 + ·OHtert-C4H9 + H2O
Reaction order:   2
Temperature:   250 - 1000 K
Pressure:  1.01 bar
Rate expression:   1.68x10-13 [cm3/molecule s] (T/298 K)2.00 e5912 [J/mole]/RT
Bath gas:   N2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
250 2.03E-12
300 1.82E-12
350 1.76E-12
400 1.79E-12
450 1.86E-12
500 1.96E-12
550 2.08E-12
600 2.22E-12
650 2.38E-12
700 2.56E-12
750 2.74E-12
800 2.94E-12
850 3.15E-12
900 3.37E-12
950 3.60E-12
1000 3.85E-12