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Title: The gas-phase decomposition of methylsilane. Part III. Kinetics
Journal: Int. J. Chem. Kinet.
Volume: 16
Page(s): 31 - 39
Year: 1984
Reference type: Journal article
Squib: 1984SAW/ONE31-39
Reaction:
CH3SiD3 → HD + CH2=SiD2
Reaction order:
1
Temperature:
1120 - 1250
K
Pressure: 6.27 bar
Rate expression:
2.0x1014 [s-1] e-271052 [J/mole]/RT
Bath gas:
CH3SiD3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1120 | 4.57E1 |
| 1125 | 5.20E1 |
| 1150 | 9.77E1 |
| 1175 | 1.79E2 |
| 1200 | 3.18E2 |
| 1225 | 5.54E2 |
| 1250 | 9.43E2 |