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Author(s):   Sawrey, B.A.; O'Neal, H.E.; Ring, M.A.; Coffey, D., Jr.
Title:   The gas-phase decomposition of methylsilane. Part III. Kinetics
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   31 - 39
Year:   1984
Reference type:   Journal article
Squib:   1984SAW/ONE31-39

Reaction:   CH3SiD3HD + CH2=SiD2
Reaction order:   1
Temperature:   1120 - 1250 K
Pressure:  6.27 bar
Rate expression:   2.0x1014 [s-1] e-271052 [J/mole]/RT
Bath gas:   CH3SiD3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1120 4.57E1
1125 5.20E1
1150 9.77E1
1175 1.79E2
1200 3.18E2
1225 5.54E2
1250 9.43E2