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Author(s):   Iyer, R.S.; Rowland, F.S.
Title:   Atom-transfer reaction rates for thermal fluorine atoms with CH3X and CF3X (X = Br, I)
Journal:   J. Phys. Chem.
Volume:   85
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981IYE/ROW2493

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1981IYE/ROW2493   CH3Br + ·FHF + ·CH2Br  283   6.09E-11              2
  1981IYE/ROW2493   CH3Br + ·FHF + ·CH2Br  283   0.40              2
  Reference reaction:  C2H2 + ·F → Adduct 2
  1981IYE/ROW2493   CH3I + ·F → Products  283   1.74E-10              2
  1981IYE/ROW2493   CH3I + ·F → Products  283   1.14              2
  Reference reaction:  C2H2 + ·F → Adduct 2
  1981IYE/ROW2493   CF3I + ·F·CF3 + IF  283   1.62E-10              2
  1981IYE/ROW2493   CF3I + ·F·CF3 + IF  283   1.06              2
  Reference reaction:  C2H2 + ·F → Adduct 2

Search returned 6 records.