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Author(s):   Iyer, R.S.; Rowland, F.S.
Title:   Atom-transfer reaction rates for thermal fluorine atoms with CH3X and CF3X (X = Br, I)
Journal:   J. Phys. Chem.
Volume:   85
Year:   1981
Reference type:   Journal article
Squib:   1981IYE/ROW2493

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1981IYE/ROW2493   CH3Br + ·FHF + ·CH2Br  283   6.09E-11              2
  1981IYE/ROW2493   CH3Br + ·FHF + ·CH2Br  283   0.40              2
  Reference reaction:  C2H2 + ·F → Adduct 2
  1981IYE/ROW2493   CH3I + ·F → Products  283   1.74E-10              2
  1981IYE/ROW2493   CH3I + ·F → Products  283   1.14              2
  Reference reaction:  C2H2 + ·F → Adduct 2
  1981IYE/ROW2493   CF3I + ·F·CF3 + IF  283   1.62E-10              2
  1981IYE/ROW2493   CF3I + ·F·CF3 + IF  283   1.06              2
  Reference reaction:  C2H2 + ·F → Adduct 2

Search returned 6 records.