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Title: Depletion kinetics of niobium atoms in the gas phase
Journal: J. Phys. Chem. A
Volume: 101
Page(s): 3348 - 3355
Year: 1997
Reference type: Journal article
Squib: 1997MCC/CAM3348-3355
Reaction:
SF6 + Nb → Other Products + SF5
Reaction order:
2
Temperature:
297 - 531
K
Pressure: 2.67E-2 bar
Rate expression:
1.2x101 [cm3/molecule s] e-20121 [±803 J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 297 | 3.47E-3 |
| 300 | 3.77E-3 |
| 325 | 7.01E-3 |
| 350 | 1.19E-2 |
| 375 | 1.89E-2 |
| 400 | 2.83E-2 |
| 425 | 4.04E-2 |
| 450 | 5.54E-2 |
| 475 | 7.36E-2 |
| 500 | 9.49E-2 |
| 525 | 1.20E-1 |
| 531 | 1.26E-1 |