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Accessibility information
Author(s):   Pritchard, H.O.; Pyke, J.B.; Trotman-Dickenson, A.F.
Title:   The study of chlorine atom reactions in the gas phase
Journal:   J. Am. Chem. Soc.
Volume:   77
Year:   1955
Reference type:   Journal article
Squib:   1955PRI/PYK2629

Reaction:   neo-C5H12 + ·ClNeopentyl + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Reference reaction order:   2
Temperature:   298 - 484 K
Pressure:  0.13 - 0.31 bar
Rate expression:   1.03 e1247 [±167121 J/mole]/RT
Bath gas:   C2H6
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.70E0
300 1.70E0
325 1.63E0
350 1.58E0
375 1.54E0
400 1.50E0
425 1.47E0
450 1.44E0
475 1.41E0
484 1.40E0