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Accessibility information
Author(s):   Mitchell, T.J.; Benson, S.W.
Title:   Modelling of the homogeneously catalyzed and uncatalyzed pyrolysis of neopentane: thermochemistry of the neopentyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   931 - 955
Year:   1993
Reference type:   Journal article
Squib:   1993MIT/BEN931-955

Reaction:   neo-C5H12 + ·ClNeopentyl + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Reference reaction order:   2
Temperature:   296 - 753 K
Rate expression:   1.42 e790 [±165 J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
296 1.96E0
300 1.95E0
325 1.90E0
350 1.86E0
375 1.83E0
400 1.80E0
425 1.78E0
450 1.75E0
475 1.73E0
500 1.72E0
525 1.70E0
550 1.69E0
575 1.68E0
600 1.66E0
625 1.65E0
650 1.64E0
675 1.63E0
700 1.63E0
725 1.62E0
750 1.61E0
753 1.61E0