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Accessibility information
Author(s):   Atkinson, R.; Pitts, J.N., Jr.
Title:   Absolute Rate Constants for the Reaction of O(3P) Atoms with a Series of Olefins over the Temperature Range 298-439oK
Journal:   J. Chem. Phys.
Volume:   67
Year:   1977
Reference type:   Journal article
Squib:   1977ATK/PIT38

Reaction:   (E)-2-C4H8 + → Products
Reaction order:   2
Temperature:   298 - 439 K
Pressure:  3.47E-2 bar
Rate expression:   2.26x10-11 [cm3/molecule s] e83.14 [±8314472 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.34E-11
300 2.33E-11
325 2.33E-11
350 2.32E-11
375 2.32E-11
400 2.32E-11
425 2.31E-11
439 2.31E-11