Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help

Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

NIST home page

MML home page

Chemical Sciences Division
  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Atkinson, R.; Pitts, J.N., Jr.
Title:   Absolute Rate Constants for the Reaction of O(3P) Atoms with a Series of Olefins over the Temperature Range 298-439oK
Journal:   J. Chem. Phys.
Volume:   67
Page(s):  
Year:   1977
Reference type:   Journal article
Squib:   1977ATK/PIT38

Reaction:   (E)-2-C4H8 + O· → Products
Reaction order:   2
Temperature:   298 - 439 K
Pressure:  3.47E-2 bar
Rate expression:   2.26x10-11 [cm3/molecule s] e83.14 [±8314472 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.34E-11
300 2.33E-11
325 2.33E-11
350 2.32E-11
375 2.32E-11
400 2.32E-11
425 2.31E-11
439 2.31E-11