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Author(s):   Borduas, N.; da Silva, G.; Murphy, J. G.; Abbatt, J. P. D.
Title:   Experimental and Theoretical Understanding of the Gas Phase Oxidation of Atmospheric Amides with OH Radicals: Kinetics, Products, and Mechanisms
Journal:   J. Phys. Chem. A
Volume:   119
Page(s):   4298 - 4308
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015BOR/DA 4298-4308

Reaction:   CH3CONHCH3 + ·OH → Products
Reaction order:   2
Reference reaction:   n-C4H9OH + ·OH → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   5.42x10-12 [±1.9x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The uncertainty reported represents the standard deviation of multiple experiments and is less than a 10% error. An additional uncertainty arises from the rate coefficient of the reference compound, and consequently, a total uncertainty closer to 20% should be considered when using these rate coefficients.

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