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 Author(s):   Atkinson, R.
Title:   Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
Journal:   Atmos. Chem. Phys.
Volume:   3
Page(s):   2233 - 2307
Year:   2003
Reference type:   Journal article
Squib:   2003ATK2233-2307

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003ATK2233-2307   CH4 + ·OH → Other Products + H2O  190 - 1240   1.76E-13   2.82   8206   6.40E-15  2
  2003ATK2233-2307   CH3D + ·OH → Other Products + H2O  240 - 430   4.61E-13   2.00   1.11E04   5.28E-15  2
  2003ATK2233-2307   CH2D2 + ·OH → Other Products + H2O  270 - 360   2.18E-12       1.60E04   3.40E-15  2
  2003ATK2233-2307   CHD3 + ·OH → Other Products + H2O  270 - 360   1.46E-12       1.64E04   1.95E-15  2
  2003ATK2233-2307   CD4 + ·OH → Other Products + H2O  240 - 800   5.06E-13   2.00   1.56E04   9.15E-16  2
  2003ATK2233-2307   C2H6 + ·OH → Other Products + H2O  180 - 1230   1.32E-12   2.00   4149   2.48E-13  2
  2003ATK2233-2307   C3H8 + ·OH → Other Products + H2O  190 - 1220   1.47E-12   2.00   723   1.09E-12  2
  2003ATK2233-2307   1-C4H10 + ·OH → Other Products + H2O  230 - 760   1.61E-12   2.00   -948   2.36E-12  2
  2003ATK2233-2307   iso-C4H10 + ·OH → Other Products + H2O  210 - 1150   1.04E-12   2.00   -1771   2.12E-12  2
  2003ATK2233-2307   n-C5H12 + ·OH → Other Products + H2O  220 - 760   2.24E-12   2.00   -1314   3.80E-12  2
  2003ATK2233-2307   neo-C5H12 + ·OH → Neopentyl + H2O  280 - 910   1.65E-12   2.00   1721   8.25E-13  2
  2003ATK2233-2307   1-C6H14 + ·OH → Other Products + H2O  290 - 970   7.57E-12   1.00   931   5.20E-12  2
  2003ATK2233-2307   (CH3)3CCH2CH3 + ·OH → Other Products + H2O  240 - 330   3.37E-11       6726   2.23E-12  2
  2003ATK2233-2307   2,3-Dimethylbutane + ·OH → Other Products + H2O  240 - 1220   1.47E-12   2.00   -3384   5.78E-12  2
  2003ATK2233-2307   1-C7H16 + ·OH → Other Products + H2O  290 - 1090   1.73E-12   2.00   -3376   6.76E-12  2
  2003ATK2233-2307   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  240 - 760   8.17E-13   2.00   -3816   3.81E-12  2
  2003ATK2233-2307   1-C8H18 + ·OH → Other Products + H2O  290 - 1080   2.42E-12   2.00   -3002   8.11E-12  2
  2003ATK2233-2307   2,2,4-Trimethylpentane + ·OH → Other Products + H2O  290 - 1190   2.09E-12   2.00   -1164   3.34E-12  2
  2003ATK2233-2307   2,2,3,3-Tetramethylbutane + ·OH → H2O + (CH3)3CC(CH3)2CH2  290 - 1180   1.77E-12   2.00   1480   9.72E-13  2
  2003ATK2233-2307   1-C9H20 + ·OH → Other Products + H2O  290 - 1100   2.25E-12   2.00   -3625   9.70E-12  2
  2003ATK2233-2307   1-C10H22 + ·OH → Other Products + H2O  290 - 1110   2.82E-12   2.00   -3376   1.10E-11  2
  2003ATK2233-2307   Cyclopropane + ·OH → Cyclopropyl + H2O  200 - 460   3.74E-13   2.00   3775   8.15E-14  2
  2003ATK2233-2307   Cyclobutane + ·OH → Cyclobutyl + H2O  270 - 370   1.86E-12   2.00   -208   2.03E-12  2
  2003ATK2233-2307   Cyclopentane + ·OH → Cyclopentyl + H2O  270 - 1200   2.42E-12   2.00   -1779   4.97E-12  2
  2003ATK2233-2307   Cyclohexane + ·OH → Cyclohexyl + H2O  290 - 500   2.90E-12   2.00   -2178   6.97E-12  2
  2003ATK2233-2307   CH4 + ·OH → Other Products + H2O  298   6.40E-15           6.40E-15  2
  2003ATK2233-2307   CH3D + ·OH → Other Products + H2O  298   5.28E-15           5.28E-15  2
  2003ATK2233-2307   CH2D2 + ·OH → Other Products + H2O  298   3.40E-15           3.40E-15  2
  2003ATK2233-2307   CHD3 + ·OH → Other Products + H2O  298   1.95E-15           1.95E-15  2
  2003ATK2233-2307   CD4 + ·OH → Other Products + H2O  298   9.16E-16           9.16E-16  2
  2003ATK2233-2307   C2H6 + ·OH → Other Products + H2O  298   2.48E-13           2.48E-13  2
  2003ATK2233-2307   C3H8 + ·OH → Other Products + H2O  298   1.09E-12           1.09E-12  2
  2003ATK2233-2307   1-C4H10 + ·OH → Other Products + H2O  298   2.36E-12           2.36E-12  2
  2003ATK2233-2307   iso-C4H10 + ·OH → Other Products + H2O  298   2.12E-12           2.12E-12  2
  2003ATK2233-2307   n-C5H12 + ·OH → Other Products + H2O  298   3.80E-12           3.80E-12  2
  2003ATK2233-2307   iso-C5H12 + ·OH → Other Products + H2O  298   3.60E-12           3.60E-12  2
  2003ATK2233-2307   neo-C5H12 + ·OH → Neopentyl + H2O  298   8.25E-13           8.25E-13  2
  2003ATK2233-2307   1-C6H14 + ·OH → Other Products + H2O  298   5.20E-12           5.20E-12  2
  2003ATK2233-2307   (CH3)2CH(CH2)2CH3 + ·OH → Other Products + H2O  298   5.20E-12           5.20E-12  2
  2003ATK2233-2307   (C2H5)2CHCH3 + ·OH → Other Products + H2O  298   5.20E-12           5.20E-12  2
  2003ATK2233-2307   (CH3)3CCH2CH3 + ·OH → Other Products + H2O  298   2.23E-12           2.23E-12  2
  2003ATK2233-2307   2,3-Dimethylbutane + ·OH → Other Products + H2O  298   5.78E-12           5.78E-12  2
  2003ATK2233-2307   1-C7H16 + ·OH → Other Products + H2O  298   6.76E-12           6.76E-12  2
  2003ATK2233-2307   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  298   3.81E-12           3.81E-12  2
  2003ATK2233-2307   1-C8H18 + ·OH → Other Products + H2O  298   8.11E-12           8.11E-12  2
  2003ATK2233-2307   2,2,4-Trimethylpentane + ·OH → Other Products + H2O  298   3.34E-12           3.34E-12  2
  2003ATK2233-2307   2,2,3,3-Tetramethylbutane + ·OH → H2O + (CH3)3CC(CH3)2CH2  298   9.72E-13           9.72E-13  2
  2003ATK2233-2307   1-C9H20 + ·OH → Other Products + H2O  298   9.70E-12           9.70E-12  2
  2003ATK2233-2307   Pentane, 3,3-diethyl- + ·OH → Other Products + H2O  298   4.80E-12           4.80E-12  2
  2003ATK2233-2307   1-C10H22 + ·OH → Other Products + H2O  298   1.10E-11           1.10E-11  2
  2003ATK2233-2307   1-C11H24 + ·OH → Other Products + H2O  298   1.23E-11           1.23E-11  2
  2003ATK2233-2307   Dodecane + ·OH → Other Products + H2O  298   1.32E-11           1.32E-11  2
  2003ATK2233-2307   CH3(CH2)11CH3 + ·OH → Other Products + H2O  298   1.51E-11           1.51E-11  2
  2003ATK2233-2307   Cyclopropane + ·OH → Cyclopropyl + H2O  298   8.15E-14           8.15E-14  2
  2003ATK2233-2307   Cyclobutane + ·OH → Cyclobutyl + H2O  298   2.03E-12           2.03E-12  2
  2003ATK2233-2307   Cyclopentane + ·OH → Cyclopentyl + H2O  298   4.97E-12           4.97E-12  2
  2003ATK2233-2307   Cyclohexane + ·OH → Cyclohexyl + H2O  298   6.97E-12           6.97E-12  2
Search returned 57 records.