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Author(s):   Arican, M.H.; Potter, E.; Whytock, D.A.
Title:   Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Year:   1973
Reference type:   Journal article
Squib:   1973ARI/POT1811

Reaction:   1-C4H10 + ·CF3CHF3 + sec-C4H9
Reaction order:   2
Temperature:   314 - 443 K
Pressure:  5.71E-2 - 0.16 bar
Rate expression:   2.24x10-13 [cm3/molecule s] e-23364 [J/mole]/RT
Bath gas:   CF3I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
314 2.91E-17
325 3.94E-17
350 7.31E-17
375 1.25E-16
400 1.99E-16
425 3.01E-16
443 3.94E-16